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2 / 4 page ![]() detect position in either a one-dimensional or a two-dimen- sional sense.[2] When light is shone onto any p±n junction, electron±hole pairs are generated on both sides of the junc- tion and carriers move down the potential gradient, with minority electrons moving from the p-side to the n-side and minority holes moving from the n-side to the p-side. This sets up a forward bias and a transverse photovoltage is set upÐ this is the basic mechanism of a solar cell output voltage, when the whole receiver surface is illuminated with light. If now a spot of light is shone on a junction that has one layer that is much more conductive than the other, a lateral photo- voltage is also set up and we can observe a voltage parallel to the plane of the junction. As before, electrons and holes are generated on both sides of the junction, and the minority carriers are swept across the junction. The photogenerated carriers are swept down the built-in potential to the highly conducting layer, and spread rapidly in this plane, forming an equipotential layer. These carriers from the equipotential layer then re-inject into the less conductive layer. In this low- conductivity layer, slow-moving excess carriers are still located in the region of the light spot. It is the tendency of these bunched carriers to recombine with the re-injected car- riers that constitute the lateral photovoltage. This photovol- tage is a measure of the location of the light beam. Further- more, the linear behavior of the incremental change in the voltage with distance along the receiver surface indicates the sensitivity, or the usefulness of the sensor.[6] This is the photo- voltaic mode and Figure 1 shows a simplified crystalline example of a PSD in this mode. If however, the device is reverse biased, re-injection is inhibited by the increased potential barrier, recombination is reduced, and the same con- tacts can be used to collect currents flowing in the base layer. In this case, current can be used to measure the location of the beam. This is the photodiode mode. Amorphous silicon devices, such as those based on p±i±n and similar structures, follow the same general principles but the precise carrier flow mechanisms are more complex. As with p±i±n solar cells, electron±hole pair generation occurs in the intrinsic layer and carriers are then separated by the junc- tion potentials so that electrons move to the n-layer and holes to the p-layer. These p±i±n structures can be configured as one- or two-dimensional devices and are widely researched. Mechanisms and properties of these devices are extensively discussed in the literature.[4,7±10] Our workis focused on the optimization of the actual thin- film PSD structure so that we have concentrated mainly on one-dimensional devices with some two-dimensional devices constructed. We have designed a novel configuration compris- ing an indium tin oxide (ITO) layer, followed by an a-Si film and a platinum layer, and a typical configuration, which forms a Schottky barrier device, is shown in Figure 2. 3. a-Si-based Position-Sensitive Detectors PSDs based on crystalline structure have been widely reported[11] but major drawbacks of these devices are their limited area and high relative costs. These comparatively small devices require complex and expensive optical systems to ensure maximum utilization of their areas and to minimize inherent discontinuities.[3] Research devices are often made with pathlengths in the region of 20 mm, while commercial devices range from 2.5 mm to about 30 mm. Our devices, both crystalline and amorphous silicon, range from 16 mm to 20 mm by 10 mm. Thin-film amorphous silicon is a well-established technol- ogy nmaterial?n used extensively for the fabrication of solar cells.[12,13] In a position-sensitive detector it can be deposited as a transparent film, which makes it possible to utilize it for angular detection.[9] It also has a number of inherent advan- tages, including low-temperature processing capabilities, high photosensitivity and short detector response times of ls.[10] Its main drawbackis the high defect state density, which can be greatly reduced using hydrogenation. Amorphous silicon can be prepared using many techniques, among the more common ones are radiofrequency (RF) and direct current (DC) glow discharge, RF sputtering, chemical vapor deposition (CVD), plasma-enhanced chemical vapor deposition (PECVD), and ion discharge. Most of the latest workis on a-Si:H PSDs fabri- cated using PECVD p±i±n structures.[4,10] These doped struc- tures produce excellent linearity between voltage output and position. Of the plasma techniques, glow discharge and sput- tering, the former has received the most attention probably due to its ability to produce films with superior optical and electrical properties[14] but reactive sputtering deposition has the advantage of permitting good control of the hydrogen content of the amorphous silicon.[15] Since the hydrogen con- tent of a-Si:H has a major effect on the optical and electrical 2 Ó WILEY-VCH Verlag GmbH, D-69469 Weinheim, 2001 0935-9648/01/12±1307-02 $ 17.50+.50/0 Adv. Mater. 2001, 13, No. 12±13, July 4 J. Henry, J. Livingstone/Thin-Film Amorphous Silicon Position-Sensitive Detectors Fig. 1. A crystalline PSD configured for measurement in photovoltaic mode. Fig. 2. A typical thin-film Schottky barrier device structure. |
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